Search results for "hybrid composite"

showing 10 items of 24 documents

Effect of Low-Intensity Pulsed Ultrasound on Osteogenic Human Mesenchymal Stem Cells Commitment in a New Bone Scaffold

2017

Purpose Bone tissue engineering is helpful in finding alternatives to overcome surgery limitations. Bone growth and repair are under the control of biochemical and mechanical signals; therefore, in recent years several approaches to improve bone regeneration have been evaluated. Osteo-inductive biomaterials, stem cells, specific growth factors and biophysical stimuli are among those. The aim of the present study was to evaluate if low-intensity pulsed ultrasound stimulation (LIPUS) treatment would improve the colonization of an MgHA/Coll hybrid composite scaffold by human mesenchymal stem cells (hMSCs) and their osteogenic differentiation. LIPUS stimulation was applied to hMSCs cultured on …

0301 basic medicineMaterials scienceCellular differentiation0206 medical engineeringLow intensity pulsed ultrasoundBiomedical EngineeringBiophysicsBioengineeringHuman mesenchymal stem cell02 engineering and technologyLow-intensity pulsed ultrasoundHuman mesenchymal stem cellsBiomaterials03 medical and health sciencesTissue ScaffoldTissue engineeringTissue scaffoldsOsteogenesisOsteogenic differentiationHumansOriginal Research ArticleCells CulturedBone growthTissue EngineeringTissue ScaffoldsOsteogenesiMesenchymal stem cellCell DifferentiationMesenchymal Stem CellsBone scaffoldGeneral MedicineMgHA/Coll hybrid composite scaffold020601 biomedical engineeringMesenchymal Stem Cell030104 developmental biologyUltrasonic WavesLow intensity pulsed ultrasoundsHumanBiomedical engineeringJournal of Applied Biomaterials & Functional Materials
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Exceptional affinity of nanostructured organic-inorganic hybrid materials towards dioxygen: confinement effect of copper complexes

2007

We report the exceptional reactivity towards dioxygen of a nanostructured organic-inorganic hybrid material due to the confinement of copper cyclam within a silica matrix. The key step is the metalation reaction of the ligand, which can occur before or after xerogel formation through the sol-gel process. The incorporation of a Cu(II) center into the material after xerogel formation leads to a bridged Cu(I)/Cu(II) mixed-valence dinuclear species. This complex exhibits a very high affinity towards dioxygen, attributable to auto-organization of the active species in the solid. The remarkable properties of these copper complexes in the silica matrix demonstrate a high cooperative effect for O(2…

Cations DivalentMetalationInorganic chemistrychemistry.chemical_elementLigands010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundAdsorptionHeterocyclic CompoundsCyclamPolymer chemistryOrganometallic CompoundsLamellar structureReactivity (chemistry)ComputingMilieux_MISCELLANEOUSdioxygen bindingBinding Sites010405 organic chemistryLigandsol-gel processesSpectrum AnalysisOrganic ChemistryTemperatureGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistrySilicon DioxideCopperEnzymesNanostructuresPeroxides0104 chemical sciencesOxygenchemistrytetraazamacrocyclesMultiprotein Complexescopper[ CHIM.MATE ] Chemical Sciences/Material chemistryAnisotropyAdsorptionHybrid materialGelsorganic-inorganic hybrid composites
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Mechanical behavior of carbon/flax hybrid composites for structural applications

2012

In this work, the influence of an unidirectional carbon fabric layer on the mechanical performances of bidirectional flax fabric/epoxy composites used for structural applications was studied. Two different bidirectional flax fabrics were used to produce flax fabric reinforced plastic (FFRP) laminates by a vacuum bagging process: one is normally used to make curtains; the other, heavier and more expensive than the previous one, is usually used as reinforcement in composite structures. In order to realize hybrid structures starting from FFRP, an unidirectional UHM carbon fabric was used to replace a bidirectional flax fabric. Tensile and three-point bending tests were performed to evaluate t…

Hybrid composite natural fiber mechanical properties vacuum baggingMaterials scienceMechanical EngineeringCarbon fibersHybrid compositevacuum baggingEpoxymechanical propertiesnatural fiberSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialiMechanics of Materialsvisual_artMaterials ChemistryCeramics and Compositesvisual_art.visual_art_mediumComposite materialLayer (electronics)Hybrid composite; mechanical properties; natural fiber; vacuum baggingNatural fiber
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Numerical investigation of the mechanical properties of a novel hybrid polymer composite reinforced with graphene and MXene nanosheets

2020

Abstract This paper presents a numerical investigation of the elastic properties of a novel hybrid polymer composite reinforced with graphene and MXene nanosheets. A finite element computational model was developed to analyze the mechanical properties of a new polymer hybrid composite reinforced with MXene and graphene taking into account the properties of the 2D nanosheets, different aspect ratios, placement options and volume fractions of nanoreinforcements, as well as the interaction effects between the nanofillers and the surrounding polymer matrix. Using the developed numerical model, the influences of the interface layer properties, MXene and graphene aspect ratio, alignment and volum…

Materials scienceGeneral Computer SciencePolymer nanocompositeComposite numberGeneral Physics and Astronomy02 engineering and technology010402 general chemistryOrthotropic material01 natural scienceslaw.inventionlawGeneral Materials ScienceComposite materialchemistry.chemical_classificationGraphenehybrid composites MXene graphene numerical simulation elastic propertiesGeneral ChemistryPolymer021001 nanoscience & nanotechnologyAspect ratio (image)0104 chemical sciencesComputational MathematicschemistryMechanics of MaterialsVolume fraction0210 nano-technologyMXenesComputational Materials Science
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A simplified predictive approach to assess the mechanical behavior of pinned hybrid composites aged in salt-fog environment

2020

Abstract Aim of this paper is to assess the predictive capabilities of a simplified theoretical approach on the failure load of aged pinned hybrid composites. In particular, the mechanical performances of glass-flax hybrid epoxy laminates exposed to salt spray fog environment, were used as input data in order to address the analytical model. Preliminarily, the relationship among mechanical performances, failure mechanisms, joint geometry and ageing time, was evaluated by double-lap joint tests on pinned samples at varying joint geometry and ageing time. The bearing and shear out limit stress of samples aged for 60 days under the salt-fog environment underwent a reduction of about 20% compar…

Materials scienceHybrid composite laminatesComposite number02 engineering and technologylaw.inventionStress (mechanics)Bearing; Failure modes; Flax; Hybrid composite laminates; Salt-fog aging0203 mechanical engineeringlawFlaxComposite materialJoint (geology)Reliability (statistics)Civil and Structural EngineeringBearing (mechanical)Failure modeEpoxy021001 nanoscience & nanotechnologyShear (sheet metal)020303 mechanical engineering & transportsSettore ING-IND/22 - Scienza E Tecnologia Dei Materialivisual_artBearingCeramics and Compositesvisual_art.visual_art_mediumsalt‐fog aging0210 nano-technologyReduction (mathematics)
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Lignocellulosic fillers and graphene nanoplatelets as hybrid reinforcement for polylactic acid: Effect on mechanical properties and degradability

2020

Abstract This work investigates the effect of adding relatively low amounts of graphene nanoplatelets (GNP) to a biocomposite based on polylactic acid (PLA) and a lignocellulosic filler achieved by grinding Posidonia Oceanica leaves (Posidonia flour, PF). The ternary composites were prepared by melt extrusion and characterized from a morphological and mechanical point of view. Furthermore, hydrolytic degradation tests were performed under acidic, neutral and alkaline environment up to 900 h. Density measurements enabled to assess the degree of intraphase, i.e. the capability of polymer macromolecules to enter the voids of PF and a modified Halpin-Tsai model was presented and used to fit exp…

Materials scienceHydrolytic degradationHybrid composite02 engineering and technologyengineering.material010402 general chemistry01 natural scienceschemistry.chemical_compoundPolylactic acidFiller (materials)Ultimate tensile strengthComposite materialchemistry.chemical_classificationGeneral EngineeringPosidonia oceanicaPolymer021001 nanoscience & nanotechnology0104 chemical sciencesGrindingSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryCeramics and CompositesengineeringBiocompositeGrapheneHalpin-tsai0210 nano-technologyTernary operationMacromolecule
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Novel hybrid polymer composites with graphene and MXene nano-reinforcements: computational analysis

2021

This paper presents a computational analysis on the mechanical and damage behavior of novel hybrid polymer composites with graphene and MXene nano-reinforcements targeted for flexible electronics and advanced high-strength structural applications with additional functions, such as real-time monitoring of structural integrity. Geometrical models of three-dimensional representative volume elements of various configurations were generated, and a computational model based on the micromechanical finite element method was developed and solved using an explicit dynamic solver. The influence of the geometrical orientation, aspect ratio, and volume fractions of the inclusions, as well as the interfa…

Materials sciencePolymers and Plastics02 engineering and technology010402 general chemistry01 natural sciencesArticleModellinglaw.inventionlcsh:QD241-441hybrid composites; MXene; graphene; modelling; damagemodellingMatrix (mathematics)lcsh:Organic chemistrylawNano-Hybrid compositesComposite materialReinforcementGraphenegrapheneGeneral ChemistrySolver021001 nanoscience & nanotechnologyAspect ratio (image)Flexible electronicsFinite element method0104 chemical sciencesDamageGraphene0210 nano-technologyhybrid compositesMXenedamage
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Pinned hybrid glass-flax composite laminates aged in salt-fog environment: Mechanical durability

2019

The aim of the present paper is to study the mechanical performance evolution of pinned hybrid glass-flax composite laminates under environment aging conditions. Hybrid glass-flax fibers/epoxy pinned laminates were exposed to salt-spray fog environmental conditions up to 60 days. With the purpose of assessing the relationship between mechanical performances and failure mechanisms at increasing aging time, single lap joints at varying joint geometry (i.e., hole diameter D and hole distance E from free edge) were characterized after 0 days (i.e., unaged samples), 30 days, and 60 days of salt-fog exposition. Based on this approach, the property&ndash

Materials sciencePolymers and PlasticsComposite number02 engineering and technologyBearing; Failure modes; Glass-flax hybrid coposites; Pinned joints; Salt fog aging010402 general chemistry01 natural sciencesFailure modesArticlelcsh:QD241-441lcsh:Organic chemistryFlexural strengthGlass-flax hybrid copositesComposite materialJoint (geology)Natural fiberPinned jointsFailure modeGeneral ChemistryEpoxyComposite laminates021001 nanoscience & nanotechnologyDurabilityGlass-flax hybrid compositePinned joint0104 chemical sciencesSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialiLap jointSalt fog agingvisual_artBearingvisual_art.visual_art_medium0210 nano-technology
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Experimental assessment of the improved properties during aging of flax/glass hybrid composite laminates for marine applications

2018

The investigation for natural fibers composites in terms of performance, durability, and environmental impact for structural applications in marine environments is a relevant challenge in scientific and industrial field. On this context, the aim of this work is to assess the durability and mechanical stability in severe environment of epoxy/glass–flax hybrid composites. For the sake of comparison, also full flax and glass epoxy composites were investigated. All samples were exposed to salt–fog environmental conditions up to 60 aging days. Wettability behavior during time was compared with water uptake evolution to assess water sensitivity of hybrid composite configurations. Moreover, quasi-…

Materials sciencePolymers and PlasticsGlass fiber02 engineering and technologyGeneral ChemistryComposite laminates010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesDurability0104 chemical sciencesSurfaces Coatings and Filmsnatural fibershybrid compositeMaterials Chemistrydurabilitymechanical propertieComposite material0210 nano-technologydurability; glass fibers; hybrid composites; mechanical properties; natural fibers; Chemistry (all); Surfaces Coatings and Films; Polymers and Plastics; Materials Chemistry2506 Metals and Alloysglass fiberJournal of Applied Polymer Science
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Effect of glass fiber hybridization on the durability in salt-fog environment of pinned flax composites

2021

The aim of the present paper is to evaluate the effect of the hybridization with external layers of glass fibers on the durability of flax fiber reinforced composites in severe aging conditions. To this scope, full glass, full flax and hybrid glass–flax pinned laminates were exposed to a salt-fog environment for up to 60 days. Double-lap pinned joint tests were performed to assess the pin-hole joints performances at varying the laminate stacking sequence. In order to better discriminate the relationship between the mechanical behavior and the fracture mechanisms of joints at increasing the aging time, different geometries (i.e., by varying both the hole diameter D and the free edge distance…

Materials sciencePolymers and PlasticsHybrid composite laminatesGlass fiberStackingOrganic chemistrySalt-fog agingFailure modesArticlelaw.inventionFlax fiberBearing; Failure modes; Flax; Hybrid composite laminates; Salt-fog agingbearing; salt-fog aging; flax; failure modes; hybrid composite laminatesQD241-441lawFlaxBearing capacityComposite materialJoint (geology)Bearing (mechanical)General ChemistryDurabilitySettore ING-IND/22 - Scienza E Tecnologia Dei MaterialiBearingFracture (geology)Bearing Failure modes Flax Hybrid composite laminates Salt-fog aging
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